Assessment of Organochlorine pesticides in cocoa beans from Ashanti and Brong Ahafo regions of Ghana
Abstract
Research was conducted in the Ashanti and Brong Ahafo regions of Ghana to determine
organochlorine pesticide residues in cocoa beans. The pesticides were extracted by using solvent
extraction technique followed by clean up with C-18 and Envi – Carb NH2 solid-phase extraction
cartridges. Extracts were dissolved in ethyl acetate and analysis carried out by Gas
Chromatograph equipped with Electron Capture Detector. Retention times were used for
identification of pesticides and quantified using external calibration method. From this study,
55.5 % of cocoa beans sampled from Brong Ahafo region and 66.7 % of cocoa beans sampled
from the Ashanti region had organochlorine pesticide residue concentrations above the EU
permissible levels. Heptachlor had the maximum concentration of residues whilst heptachlor exo
epoxide had the minimum concentration for the two regions. The results obtained reflect the
enormous past use and continual usage of pesticides on cocoa beans in Ghana.
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