USO DE ESPECTROSCOPÍA INFRARROJA CON TRANSFORMADA DE FOURIER Y pH ENEL ESTUDIO DE CONGLOMERANTES PARA MORTEROS MIXTOS
Abstract
This work presents the advances of research in conglomerates for mixed mortars, an important search of new and modified conglomerating materials is developed for its use in works of restoration of the Cultural Heritage, taking into account an experimental methodology, with four main conglomerates (Portland gray cement) , fat lime, hydroxyapatite and gypsum plaster); which were subjected to tests of specific gravity, infrared spectroscopy (IR) and pH measurement to evaluate the existence of carbonation; and then compare the results obtained. It is concluded: the mortar with gray cement, has a high concentration of calcium hydroxide, considerable alkalinity is produced, with a pH equal to 12.5. The carbon dioxide, responsible for carbonation,
reduces the pH of the mortar, depassivating the steel facilitating the attack of substances. Contrary to the foregoing, in gypsum plaster the peak 455 cm -1 of the IR, leads to the deformation of ferrite in austenite; what is reflected in the solubility of the mixture, which increases the thermal insulation. And also, the functional component of amorphous sulfates achieving greater compactness of the mixed mortar, the pH in the fat lime of 12.74 does not represent acidity and turns the mortar into a durable material.
Downloads
References
Piqué, T., & Vázquez, A. USO DE ESPECTROSCOPIA INFRARROJA CON TRANSFORMADA DE FOURIER(FTIR) EN EL ESTUDIO DE LA HIDRATACIÓN DEL CEMENTO. CONCRETO Y CEMENTO . INVESTIGACIÓN Y DESARROLLO, vOL
NUM 2., 62-71. México ene. /jun. 2012.
J. Lanas, J.L. Pérez Bernal, M.A. Bello, J.I Alvarez, Mechanical properties of natural hydraulic lime-based mortars, Cem. Concr. Res. 34 (2004) 2191-2201.
J. Lanas, J.I. Alvarez, Masonry repair lime-based mortars: Factors affecting the mechanical behaviour, Cem. Concr. Res., 33 (2003) 1867-1876.
P. Degryse, J. Elsen, M. Waelkens, Study of ancient mortars from Salassos (Turkey) in view of their conservation, Cem Concr. Res. 32 (2002) 1457-1563.
5. R. Montani, La carbonatación, el enemigo olvidado del concreto. Instituto Mexicano del Cemento y Del concreto, A.C. Revista Construcción y Tecnología. Diciembre 2000.
Giraldo M, M., & Tobon, J. (2006). EVOLUCIÓN MINERALÓGICA DEL CEMENTO PORTLAND DURANTE EL PROCESO DE HIDRATACIÓN. Dyna, Año 73, Nro. 148, pp. 69-81. , 69-81.
D. R. C. Catalina Gómez Hoyos, “Evaluación del curado de resinas fenólicas tipo novolaca modificadas con lignina por espectroscopia infrarroja”, Universidad Pontificia Bolivariana, 2008.
IR, SEM and Vicat techniques”, en Cement and Concrete Research, vol. 39, núm. 5, pp. 433-439, May 2009.
Briceño, Gravedad Específica: Fórmula y Unidades, Cómo Calcularla. Lifeder. Mayo de 2018.
J. M, Método de ensayo para determinar el peso específico del cemento hidráulico. Ingeniera civil. Octubre de 2008.
J. D. Osorio, Carbonatación del concreto: ¿Cómo detectarla? 360 en concreto. Junio 2012.
J.A Rivera; G. Fetter; P. Bosch, Efecto del pH en la síntesis de hidroxiapatita en presencia de microondas, Materia (Rio J.) vol.15 no.4 Rio de Janeiro 2010.
A.U.Florez,O.Z. Giraldo, ‘’Desarrollo de matrices compuestas basadas en alcohol polivinilico e hidroxiapatita para uso potencial en ingeniería de tejido óseo’’ Instituto Tecnológico Metropolitano, 2018.
Z. Li, Advanced Concrete Technology, John Wiley & Sons, Inc., 2011.
Copyright (c) 2019 IJRDO - Journal of Applied Science (ISSN: 2455-6653)
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Author(s) and co-author(s) jointly and severally represent and warrant that the Article is original with the author(s) and does not infringe any copyright or violate any other right of any third parties, and that the Article has not been published elsewhere. Author(s) agree to the terms that the IJRDO Journal will have the full right to remove the published article on any misconduct found in the published article.